二面角
化学
戒指(化学)
苯
氢键
结晶学
离子
晶体结构
立体化学
分子
有机化学
作者
Suchada Chantrapromma,B. Jindawong,Hoong‐Kun Fun
标识
DOI:10.1107/s1600536807061922
摘要
In the title salt, C19H18NO2+·C7H7SO3−, the C=C double bond in the cation has an E configuration. The cation is not planar as the dihedral angle between the quinolinium and benzene ring systems is 14.74 (8)°. The anion is aligned approximately perpendicularly to the cation, with the benzene ring of the anion making dihedral angles of 89.98 (8) and 75.36 (10)° with the quinolinium and benzene ring systems of the cation, respectively. An intramolecular O—H⋯O hydrogen bond between the hydroxy and methoxy groups generates an S(5) ring motif. The cations link with anions through weak C—H⋯O interaction into cation–anion pairs along the b direction, and the adjacent pairs are further linked by O—H⋯O hydrogen bonds and weak C—H⋯O interactions into a three-dimensional network. The crystal is further stabilized by C—H⋯π interactions, and π–π interactions [centroid–centroid distances of 3.5236 (12) and 3.5337 (12) Å] are also observed.
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