化学
催化作用
功能群
反应条件
组合化学
光催化
吡咯烷酮类
光化学
有机化学
聚合物
光催化
作者
Xiao‐Xiao Liu,Jia Jia,Ze Wang,Yu‐Ting Zhang,Jiao Chen,Ke Yang,Chun‐Yang He,Liang Zhao
标识
DOI:10.1002/adsc.202000342
摘要
Abstract Fluorinated aziridines are very important structural motifs, but methods access to such structures are still very rare. In this paper, we report a mild, catalyst‐free and operationally simple strategy for the direct aminofluoroalkylation of olefins driven by the noncovalent interaction between N ‐allylanilines and fluoroalkyl iodides. This photochemical transformation features synthetic simplicity, mild reaction conditions, without the use of any photoredox catalyst, and high functional group tolerance. Moreover, the structures can be used as important precursors for the synthesis of β ‐fluoroalkylated alkylamine derivatives, such as fluorinated amino acids and fluorinated 2‐pyrrolidinones. magnified image
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