Metal‐Free Bifunctional Ordered Mesoporous Carbon for Reversible Zn‐CO2 Batteries

The fabrication of Zn-CO2 batteries is a promising technique for CO2 fixation and energy storage. Herein, nitrogen-doped ordered mesoporous carbon (NOMC) is adopted as a bifunctional metal-free electrocatalyst for CO2 reduction and oxygen evolution reaction in the near-neutral electrolyte. The ordered mesoporous structures and abundant N-dopings of NOMC facilitate the accessibility and utilization of the active sites, which endow NOMC with excellent electrocatalysis performance and outstanding stability. Especially, a nearly 100% CO Faradaic efficiency is achieved at an ultralow overpotential of 360 mV for CO2 reduction. When constructed as an aqueous rechargeable Zn-CO2 battery using NOMC as the cathode, it yields a high peak power density of 0.71 mW cm-2 , a good cyclability of 300 cycles, and excellent energy efficiency of 52.8% at 1.0 mA cm-2 .