Synthesis of a new solvent-responsive pillar[5]arene-based [1]rotaxane molecular machine

In this work, we designed a new pillar[5]arene-based molecular machine responsive to the polarity of different solvents, which can exist in an interlocked structure in CDCl₃ and CD₃OD, and can exist in an extended form in DMSO and was studied by ¹H and 2D NMR spectroscopy, HR(MS) and fluorescence spectroscopy.