Recent Progress in Multivalent Metal (Mg, Zn, Ca, and Al) and Metal‐Ion Rechargeable Batteries with Organic Materials as Promising Electrodes

Abstract The emerging demand for electronic and transportation technologies has driven the development of rechargeable batteries with enhanced capacity storage. Especially, multivalent metal (Mg, Zn, Ca, and Al) and metal‐ion batteries have recently attracted considerable interests as promising substitutes for future large‐scale energy storage devices, due to their natural abundance and multielectron redox capability. These metals are compatible with nonflammable aqueous electrolytes and are less reactive when exposed in ambient atmosphere as compared with Li metals, hence enabling potential safer battery systems. Luckily, green and sustainable organic compounds could be designed and tailored as universal host materials to accommodate multivalent metal ions. Considering these advantages, effective approaches toward achieving organic multivalent metal and metal‐ion rechargeable batteries are highlighted in this Review. Moreover, organic structures, cell configurations, and key relevant electrochemical parameters are presented. Hopefully, this Review will provide a fundamental guidance for future development of organic‐based multivalent metal and metal‐ion rechargeable batteries.