材料科学
阴极
钙钛矿(结构)
图层(电子)
平面的
光电子学
金属
离子
等效串联电阻
化学工程
活动层
光活性层
能量转换效率
复合材料
聚合物太阳能电池
有机化学
物理化学
电压
化学
冶金
工程类
计算机图形学(图像)
物理
薄膜晶体管
量子力学
计算机科学
作者
Fulin Sun,Chunjun Liang,Huimin Zhang,Chao Ji,Qi Song,Hongkang Gong,Dan Li,Fangtian You,Zhiqun He
标识
DOI:10.1002/admi.202100506
摘要
Abstract Ion migration is a crucial factor influencing the stability of perovskite solar cells. Insertion of an interfacial layer between the electron‐transporting layer and the cathode is shown to be an effective way to enhance the performance of devices. However, exploring more effective interfacial materials to block ion migration and thus enhance the device stability is still needed. Herein, a series of 8‐hydroxyquinoline metal complexes are employed as cathode interfacial layers (CILs) in inverted planar perovskite solar cells. The devices with CILs exhibit better performance, stability, and reproducibility than the control device without CILs. The introduction of the CILs forms a better energy match between the [6,6]‐phenyl‐C61‐butyric acid methyl ester layer and the cathode, reduces the contact resistance, accelerates the charge transfer, and suppresses non‐radiative recombination. Moreover, the CILs protect the device from moisture and block the ion diffusions, which is beneficial for device stability. After optimization, the best power conversion efficiency of 20.6% is obtained by using 8‐hydroxyquinoline aluminum (Alq 3 ) as a CIL, and the efficiency remains 85% of its initial value after 800 h continuous illumination.
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