胶粘剂
单宁酸
氢键
耐水性
材料科学
粘附
无水的
丙烯酸酯
化学工程
儿茶酚
高分子化学
自愈水凝胶
傅里叶变换红外光谱
固化(化学)
超分子化学
化学
聚合物
复合材料
有机化学
分子
图层(电子)
单体
工程类
作者
Jueying Sun,Minghan He,Weiquan Zhao,Yi Dan,Long Jiang
标识
DOI:10.1016/j.reactfunctpolym.2021.104890
摘要
Water based polyacrylics adhesives is of great need in modern society due to their eco-friendly nature as well as cost effectiveness. However, despite the strong adhesion capability of polyacrylics in anhydrous state, achieving a reliable adhesion under moisture or underwater conditions remains a great challenge. Herein, a polyacrylates-containing supramolecular adhesive with enhanced water-resistant capability was successfully designed and fabricated by integrating tannic acid (TA) with poly(2-hydroxyethyl acrylate-co-acrylic acid) (P(HEA-co-AA)) through hydrogen-bonding driven co-assembly. The multiple hydrogen-bonding interactions between P(HEA-co-AA) and TA were investigated by FTIR and DFT calculation. Owing to the presence of abundant polar groups including carboxyl, hydroxyl, catechol and pyro-gallol, the supramolecular adhesives exhibit a maximum adhesion strength of 4.1 MPa on Al sheets, which is 1.5 times stronger than that of P(HEA-co-AA) under the same conditions. Moreover, 10 wt% of TA could dramatically increase the water resistance of P(HEA-co-AA)/TA supramolecular adhesive, which could maintain about 2.8 MPa of the joint strength on Al sheets after 3 h underwater immersion, far surpassing several commercial adhesives, and pristine P(HEA-co-AA), which is completely failed underwater. Overall, this work provided a “green” alternative to improve the water-resistance of water-based polyacrylics adhesives.
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