材料科学
超级电容器
微观结构
电容
化学工程
纳米材料
电极
碳纤维
纳米技术
成核
电化学
热液循环
复合数
复合材料
化学
工程类
物理化学
有机化学
作者
Qingyuan Niu,Zixin Feng,Kezheng Gao,Qiheng Tang,Xiankai Sun,Lizhen Wang
标识
DOI:10.1007/s11664-021-09042-z
摘要
Reasonable combination of carbon and pseudocapacitive material in a composite electrode can produce a high-performance supercapacitor. However, the nano-structured pseudocapacitive materials tend to assemble randomly into microscale bulky forms during the preparation of composite electrode materials, which suffer from a low specific surface area and a mechanically weak structure, resulting in poor electrochemical performance. In this article, a nitrogen-doped carbon/NiCo2S4 electrode material was prepared by micro-spatial hydrothermal reaction in the multicellular microstructure of auricularia. The micro-space-multicellular microstructure of auricularia can provide a huge and efficient nucleation center of NiCo2S4 nanomaterials during the hydrothermal reaction. The morphology of nitrogen-doped carbon/NiCo2S4 electrode material can be effectively controlled by changing the amount of metal ions. The stacked NiCo2S4 nanoparticles of the NC/NiCo2S4-6 electrode material exhibit a network-like structure to a certain extent. The maximum mass specific capacitance of the NC/NiCo2S4-6 electrode material is about 1131 F g−1 at a current density of 0.25 A g−1. There is 81.5% retention of its initial capacitance after 10,000 cycles. The NC/NiCo2S4 electrode material, prepared by micro-spatial hydrothermal reaction in the multicellular microstructure of auricularia, exhibits good electrochemical cycling stability.
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