TiO2 Nanostructures as Anode Materials for Li/Na‐Ion Batteries

Abstract Here we summarize some results on the use of TiO 2 nanostructures as anode materials for more efficient Li‐ion (LIBs) and Na‐ion (NIBs) batteries. LIBs are the leader to power portable electronic devices, and represent in the short‐term the most adequate technology to power electrical vehicles, while NIBs hold promise for large storage of energy generated from renewable sources. Specifically, TiO 2 an abundant, low cost, chemically stable and environmentally safe oxide represents in LIBs an alternative to graphite for applications in which safety is mandatory. For NIBs, TiO 2 anodes (or more precisely negative electrodes) work at low voltage, assuring acceptable energy density values. Finally, assembling different TiO 2 polymorphs in the form of nanostructures decreases diffusion distances, increases the number of contacts and offering additional sites for Na + storage, helping to improve power efficiency. More specifically, in this contribution we highlighted our work on TiO 2 anatase mesocrystals of colloidal size. These sophisticate materials; showing excellent textural properties, have remarkable electrochemical performance as anodes for Li/Na‐ion batteries, with conventional alkyl carbonates electrolytes and safe electrolytes based on ionic liquids.