自愈水凝胶
甲基丙烯酸缩水甘油酯
甲基丙烯酸酯
淀粉
聚合物
高分子科学
高分子化学
化学
化学工程
合成聚合物
材料科学
有机化学
共聚物
工程类
作者
Michelly Cristina Galdioli Pellá,Andressa Renatta Simão,Marcos R. Maurício,R. Auccaise,Guilherme Miranda Pereira,Rafael da Silva,Adley F. Rubira
标识
DOI:10.1016/j.carbpol.2023.120614
摘要
Chemical modification reactions and blending formation are two alternatives used to improve the properties of starch-based materials. This work used both approaches to evaluate how they would affect the properties of hydrogels. The hydrogels were based on corn starch (St), modified with glycidyl methacrylate (GMA; starch-g-GMA; GMASt), and blended with N,N′-dimethylacrylamide (DMAAm; GMAStxDMAAmy) or sodium acrylate (SA; GMAStxSAy). The results confirmed that the pure GMASt matrix had a low swelling degree (≈3 g g−1), but when blended with the synthetic polymers, this value reached ≈10 g g−1 (sample GMASt25DMAAm75). All matrices showed responsiveness towards pH variations. In general, they swelled more at pH 5 than at pH 7. While DMAAm had more influence on the swelling degree, SA was more efficient as a mechanical enhancer. Increasing 25 % of the amount of SA in the blend increased Young's Modulus by a factor of ≈10 times. It confirmed that both polymers effectively change the properties of GMASt, but in different ways.
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