荧光粉
半最大全宽
发光
发光二极管
近红外光谱
红外线的
宽带
密度泛函理论
材料科学
二极管
物理
化学
光电子学
光学
计算化学
作者
Yingze Zhu,Xuesong Wang,Jianwei Qiao,Maxim S. Мolokeev,H.C. Swart,Lixin Ning,Zhiguo Xia
标识
DOI:10.1021/acs.chemmater.2c03631
摘要
To promote the development of near-infrared (NIR) light sources in optoelectronic and biomedical applications, the discovery of NIR-emitting phosphor materials and their design principles are essential. Herein, we report a novel Eu2+-activated broadband NIR-emitting phosphor, BaSrGa4O8:Eu2+, which features multisite occupation due to Ba/Sr and oxygen site occupancy disorder. With an increase in the Ba/Sr atomic ratio from 1:1 to 1.7:0.3, the Eu2+ emission band maximum red-shifts from 670 to 775 nm, along with an enlargement of the full width at half-maximum (FWHM) from 140 to 230 nm. The underlying mechanism for the structure–property relationship is elucidated using density functional theory calculations. The application of the NIR phosphor-converted light-emitting diodes (pc-LEDs) is demonstrated, showing their potential in night-vision technology. Our results can initiate further exploitation of the host structural disorder toward Eu2+ broadband NIR luminescence for applications in pc-LEDs.
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