Impact-Protective Bicontinuous Hydrogel/Ultrahigh-Molecular Weight Polyethylene Fabric Composite with Multiscale Energy Dissipation Structures for Soft Body Armor

Soft body armor greatly improves the comfort and security of the wearers. Although laminates based on high-performance fabrics have been adopted, it remains an enormous challenge to develop fabric laminates having flexibility, low bulge deformation, and ballistic protection capability simultaneously. Herein, we report a bullet-proof bicontinuous hydrogel (BH)/ultrahigh-molecular weight polyethylene fabric (UPF) composite. The presence of the BH significantly improves the impact resistance performance of the UPF, without compromising its flexibility. In specific, the multiscale energy dissipation structures composed of hydrogen bond associations in the chain scale, bicontinuous phase structures in the nanoscale, and fibers in the microscale are broken to dissipate energy. As a result, the impact energy of the bullet is greatly absorbed and the bulge height of the composites is significantly reduced in contrast to the neat UPF laminates. This study indicates that the flexible BH-UPF composites with multiscale energy dissipation structures have a promising application in soft body armor.