化学
除氧
芳构化
酰化
试剂
废止
基质(水族馆)
组合化学
醌
有机化学
区域选择性
催化作用
海洋学
地质学
作者
Guannan Li,Hao‐Cong Li,Meng‐Ru Wang,Zhan Lu,Bing Yu
标识
DOI:10.1002/adsc.202200868
摘要
Abstract A visible‐light‐induced acylation aromatization of para ‐quinone methides to access α,α′‐diarylated ketones was realized with cheap and readily available carboxylic acids as acylating reagents via deoxygenation. The synthetic method avoids the tedious preparation of reactants or catalysts and shows a broad substrate scope (34 examples) under mild conditions. Notably, the late‐stage functionalization of some drug molecules could also be achieved via this protocol. magnified image
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