聚丁二烯
天然橡胶
聚合
微观结构
材料科学
催化作用
烷基
合成橡胶
丁苯橡胶
苯乙烯
高分子化学
纳塔
复合材料
化学工程
化学
共聚物
有机化学
聚合物
工程类
作者
Subhra Mohanty,V.K. Gupta
出处
期刊:Kirk-Othmer Encyclopedia of Chemical Technology
日期:2023-03-23
卷期号:: 1-20
标识
DOI:10.1002/0471238961.1615122508011201.a01.pub2
摘要
Abstract Polybutadiene (PBR) occupies the second position among synthetic rubber after styrene‐butadiene rubber with a global production capacity of ∼2.8 million metric tons per year. It is produced by solution polymerization process using the Ziegler‐Natta catalyst system. PBR with varied microstructure feature is produced using different types of transition metal in combination with alkyl aluminum. The presence of different microstructures in the product impact properties and performances of the rubber. This article focuses on PBR polymerization processes with different types of catalyst systems and their effect on microstructure of products.
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