Chloride‐Induced Selectfluor Activated Fluorothiolation of Alkenes to Access β‐Fluorothioether

Abstract This study describes a chloride‐induced three‐component fluorothiolation of alkenes with arylthiophenols and selectfluor, facilitating efficient synthesis of β ‐fluorothioether. The protocol exhibits good functional group compatibility, mild reaction conditions, good yield, and readily available reagents. Importantly, this study presents an unprecedented radical‐involved process for fluorothiolation.