Lignin-coordinated highly dispersed Pd Zn alloy nanocluster supported on N-doped nanolayer carbon and its application in hexavalent chromium detoxification

As a renewable and low-cost biomacromolecule with high aromaticity and carbon content, lignin is a promising raw material for preparation of versatile carbon materials. Herein, we present a facile one-pot approach to prepare PdZn alloy nanocluster catalysts supported on N-doped lignin-derived nanolayer carbon through facile pyrolysis of melamine-mixed lignin-Pd-Zn complex. The dispersion of the PdZn alloy nanoclusters could be effectively modulated by varying the addition of melamine and the molar ratio of Pd and Zn salts. PdZn alloy nanocluster catalysts (Pd-Zn29@N10C) with ultra-small particle size (about 0.47 nm) were prepared when 10 times of melamine (relative to lignin weight) was added and the molar ratio of Pd and Zn salts was 1:29. Thereby, the catalyst presented superior catalytic activity for reduction of Cr(VI) to harmfulless Cr(III), significantly better than the two references Zn@N10C (without Pd addition) and Pd-Zn29@C (without N doping), as well as the commercial Pd/C. In addition, thanks to the strong anchoring of the PdZn alloy on the N-doped nanolayer support, the Pd-Zn29@N10C catalysts also exhibited good reusability. Consequently, the current study provides a straightforward and feasible method for producing highly dispersed PdZn alloy nanoclusters by lignin coordination, and further demonstrates its excellent applicability in hexavalent chromium reduction.