Experimental insights into catalytic oxidation of 1,6-hexanediol to ε-caprolactone over (p-cymene)RuCl2(L) complexes in non-polar media

The activity-pocket site dimension ( θ c ) dependence of ( p -cymene)RuCl 2 (L) supports associative interchange mechanism for 1,6-hexandiol oxidation to ε-caprolactone. Methyl isobutyl carbinol, a H-accepting product, reacts with Ru, causing deactivation.