Tuning the interface of MIMII(OH)F@MIMII1-xS (MⅠ: Ni, Co; MⅡ: Co, Fe) by atomic replacement strategy toward high performance overall water splitting

Constructing heterostructure is considered as one of the most promising strategies to reveal high efficiency hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) performance. Nevertheless, it is highly challenging to obtain stable interfaces and sufficient active sites via conventional method. In addition, Ni, Co and Fe elements share the valence electron structures of 3d6-84s2, the appropriate integration of these metals to induce synergistic effect in multicomponent electrocatalysts can enhance electrochemical activity. Herein, in this work, the MIMII(OH)F@MIMII1-xS (NiFe(OH)F@NiFe1-xS, NiCo(OH)F@NiCo1-xS, CoFe(OH)F@CoFe1-xS) autogenous heterostructure on nickel foam are constructed. As a result, NiFe(OH)F@NiFe1-xS-0.05, NiCo(OH)F@NiCo1-xS-0.05, and CoFe(OH)F@CoFe1-xS-0.05 demonstrate outstanding overpotential for HER (70 mV, 90 mV, 81 mV at −10 mA cm−2) and OER (370 mV, 470 mV, 370 mV at 10 mA cm−2) in alkaline electrolyte, while the overpotential for HER is 176 mV, 189 mV, 167 mV at −10 mA cm−2 and corresponding OER is 290 mV, 390 mV, 300 mV at 10 mA cm−2 in simulated seawater, respectively. In addition, the NiFe, NiCo, CoFe-based electrolyzer acquire favorable overall water splitting activity in alkaline (1.72 V, 1.87 V, 1.66 V) and simulated seawater (1.73 V, 1.75 V, 1.69 V) at 10 mA cm−2. Overall, the above results authenticate the feasibility of developing autogenous heterostructure electrocatalysts for providing hydrogen and oxygen in alkaline and simulated seawater.