Ferricyanide Armed Anodes Enable Stable Water Oxidation in Saturated Saline Water at 2 A/cm2

Abstract The direct seawater electrolysis at high current density and low overpotential affords an effective strategy toward clean and renewable hydrogen fuel production. However, the severe corrosion of anode as a result of the saturation of Cl − upon continuous seawater feeding seriously hamper the electrolytic process. Herein, cobalt ferricyanide / cobalt phosphide (CoFePBA/Co 2 P) anodes with Cap/Pin structure are synthesized, which stably catalyze alkaline saturated saline water oxidation at 200–2000 mA cm −2 over hundreds of hours without corrosion. Together with the experimental findings, the molecular dynamics simulations reveal that PO 4 3− and Fe(CN) 6 3− generated by the electrode play synergistic role in repelling Cl − via electrostatic repulsion and dense coverage, which reduced Cl − adsorption by nearly 5‐fold. The novel anionic synergy endow superior corrosion protection for the electrode, and is expected to promote the practical application of saline water electrolysis.