膜
正渗透
壳聚糖
化学工程
化学
接触角
纳滤
Zeta电位
反渗透
结垢
自愈水凝胶
膜污染
色谱法
材料科学
高分子化学
有机化学
纳米颗粒
生物化学
工程类
作者
Lei Wu,Xiaolu Gong,Cong Ma,Xu Lan,Ming Li,Chen Lyu,Nian X. Sun
出处
期刊:Chemosphere
[Elsevier]
日期:2023-10-14
卷期号:345: 140411-140411
被引量:5
标识
DOI:10.1016/j.chemosphere.2023.140411
摘要
In this study, hydrogels generated by the Schiff base reaction between citral and chitosan (CS) were used for the first time to improve the anti-bacterial property of forward osmosis (FO) membranes. The composite membranes were characterized by scanning electron microscopy (SEM), Fourier transform infrared (FTIR), Water contact angle (WCA), Zeta potential and confocal laser scanning microscopic (CLSM). In the FO filtration experiment, the membrane performance of TFC-1 with 1 M sodium chloride solution as the draw solution and deionized water as the feed solution was the best, with the water flux of 25.54 ± 0.7 L m-2 h-1 and the reverse salt flux of 4.7 ± 0.4 g m-2 h-1. Although the hydrogel coating produced a certain hydraulic resistance, the flux of the modified membrane was only reduced by about 8%, compared with the unmodified membrane. However, the anti-bacterial property (Pseudomonas aeruginosa) and anti-fouling properties (bovine serum protein and lysozyme protein) of the modified membranes were improved, showing good antibacterial properties (99%) and flux recovery rate (over 90%). The modified method has the advantages of easy access to raw materials, simple operation and no risk of secondary pollution, which can effectively reduce the cost of chemical cleaning and extend the service life of the membrane. The modification of membrane by chitosan-based hydrogel is a promising option in the field of membrane anti-bacteria.
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