Organic Semiconductor Based on N, S‐Containing Crown Ether Enabling Efficient and Stable Perovskite Solar Cells

Abstract The uncoordinated lead cations are ubiquitous in perovskite films and severely affect the efficiency and stability of perovskite solar cells (PSCs). In this work, 15‐crown‐5 with various heteroatoms are connected to the organic semiconductor carbazole diphenylamine, and two new compounds, CDT‐S and CDT‐N, are developed to modify the Pb 2+ defects in perovskite films through the anti‐solvent method. Apart from the oxygen atoms, there are also N atoms on crown ether ring in CDT‐N, and both S and N heteroatoms in CDT‐S. The heteroatoms enhance the interaction between the crown ether‐based semiconductors and the undercoordinated Pb 2+ defect in perovskite. Particularly, the stronger interaction between S atoms and Pb 2+ further enhances the defect passivation effect of CDT‐S than CDT‐N, thereby more effectively suppressing the non‐radiative recombination of charge carriers. Finally, the efficiency of the device treated with CDT‐S is up to 23.05 %. Moreover, the unencapsulated device based on CDT‐S maintained 90.5 % of the initial efficiency after being stored under dark conditions for 1000 hours, demonstrating good long‐term stability. Our work demonstrates that crown ethers are promising in perovskite solar cells, and the crown ether containing multiple heteroatoms could effectively improve both efficiency and stability of devices.