Iridium-Catalyzed Migratory Terminal C(sp3)–H Amidation of Heteroatom-Substituted Internal Alkenes via Olefin Chain Walking

)-H amidation of internal alkenes utilizing dioxazolones as an amino source via olefin chain walking. Most notably, this mechanistic motif of double bond migration to the terminal position operates not only with dialkyl-substituted simple alkenes including styrenes but also with heteroatom-substituted olefins such as enol ethers, vinyl silanes, and vinyl borons, thus representing the first example of the terminal methyl amidation of the latter type of alkenes through a nondissociative chain walking process.