Carbon Nanotube Grown from Cobalt Supported on Biomass-Derived Carbon as Nanocomposite for the Attenuation of Electromagnetic Waves

碳纳米管 纳米复合材料 衰减 材料科学 生物量(生态学) 碳纤维 化学工程 复合材料 冶金 光学 物理 复合数 地质学 工程类 海洋学
作者
Qiaojun Yi,Chaolong Li,Feng Zhang,Heng Zhang,Wang Xiao,Haofei Shi,Mingxing Piao
出处
期刊:ACS applied nano materials [American Chemical Society]
卷期号:7 (20): 23763-23776
标识
DOI:10.1021/acsanm.4c04190
摘要

In applications such as aerospace, automotive, and mobile devices, reduction of weight is crucial for enhancing the performance, minimizing the energy expenditure, and extending the operational lifespan. Lightweight electromagnetic wave-absorbing materials offer a viable solution to achieve these objectives without compromising the absorption efficiency. Additionally, the cost-effective production of these materials facilitates large-scale manufacturing, thereby broadening the application scope of electromagnetic wave absorption technology. In this study, an ultralight hierarchical biomass-derived porous carbon (BPC)/Co/carbon nanotube (CNT) composite was prepared highly efficiently by employing a microwave plasma-assisted reduced chemical vapor deposition technique. Taking advantage of the renewable wood, the BPC served as the matrix, in which CNTs with magnetic Co nanoparticles were grown on the surface of the BPC. The hierarchical structure with zero-dimensional Co nanocrystals, one-dimensional CNTs, and three-dimensional BPC matrix could fertilize the loss mechanism availably, which was rationally endowed with enhanced electromagnetic wave dissipation capacity under a low loading content. Consequently, the composite demonstrated a remarkable minimum reflection loss of −78.7 dB at a thin matching thickness of 1.9 mm despite having a filler content as minimal as 10 wt %. Furthermore, the radar cross-section could be significantly reduced to 21.5 dB m2 when the detection angle was fixed at 20°. This work offers insights into designing and fabricating next-generation ultralight electromagnetic wave absorbers through a cost-effective, ecofriendly, and efficient approach.
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