Electrochemical C3‐Fluoroalkoxylation of Quinoxalin‐2(1H)‑ones with Fluoroalkyl Alcohols for the Synthesis of 3‐Fluoroalkoxylated Quinoxalin‐2(1H)‐ones

Abstract Herein, we report the first electricity‐driven and metal‐free C(3)−H fluoroalkoxylation of quinoxalin‐2(1 H )‐ones with both α ‐monosubstituted and α , α ‐disubstituted fluoroalkyl alcohols. This strategy features the advantages of convenience, mildness, effEctiveness and broad substrate practicality for synthesizing a new type of 3‐fluoroalkoxylated quinoxalin‐2(1 H )‐ones.