​The structural regulation of photosensitive unit and conjugation in COFs for efficient photocatalytic H2 evolution

The photosensitive unit and conjugation play a significant role in photocatalytic performance of covalent organic frameworks (COFs). In this work, a series of COFs that introduced the phenyl phenanthridine as photosensitive unit with different planarity of linkages were synthesized and the common regulation between them for photocatalysis hydrogen evolution reaction (HER) was also studied. The results indicate that DHTB‐PPD, with 2/3 planarity linkages (β‐ketoenamine/imine is 2/3) and the phenyl phenanthridine as building blocks, shows the narrowest bandgap and the strongest charge separation efficiency. Therefore, it shows the highest H2 production rate of 12.13 mmol g‐1 h‐1. The optimal photocatalytic efficiency of DTHB‐PPD can be attributed to the combined effect of the photosensitive unit and the long‐range ordering of the COF skeleton. According to The Density Functional Theory (DFT), the O site on β‐ketoamine is the most possible H2 generation site, but the photocatalytic efficiency of TP‐PPD, with the highest skeletal conjugation and the highest proportion of β‐ketoamine is not the most efficient photocatalyst, indicating that the long‐range ordering of COFs is important on photocatalytic performance. Thus, these findings provide valuable guidance for the structural design of COFs photocatalysts.