From Elementary to Advanced Design of Functional Metal–Organic Frameworks: A User Guide to Deciphering the Reticular Chemistry Toolbox

拓扑(电路) 块(置换群论) 计算机科学 方解石 工具箱 合理设计 纳米技术 材料科学 工程类 化学 几何学 数学 生物化学 沸石 电气工程 程序设计语言 催化作用
作者
Vincent Guillerm,Hao Jiang,Dalal Alezi,Norah Alsadun,Mohamed Eddaoudi
出处
期刊:Advanced Materials [Wiley]
被引量:2
标识
DOI:10.1002/adma.202414153
摘要

Here, the fundamental requirements are described for understanding and using topology tools in the design of porous materials, emphasizing the relationships between nets, metal-organic framework (MOF) structures, nodes, and building blocks. Common design approaches are discussed, highlighting prerequisites for the rational design of MOFs, such as those with simple pcu topology through the molecular building block approach, or axial-to-axial pillaring. The importance of highly connected nets and building units is emphasized for achieving structural predictability. The geometrical requirements are detailed for designing highly connected MOFs using more elaborate strategies: MOFs with rht topology through the supermolecular building block approach, tbo topology through the supermolecular building layer approach, and sph topology through a merged net approach The potential for innovation through deviations from default nets, such as introducing a geometry mismatch is addressed, which can lead to novel materials with unique zeolitic structures. Examples include MOFs with sodalite (sod) topology, developed through cantellation or mixed-ligand approaches inspired by ancestral architectural methods, utilizing centring structure-directing agents. Key insights for researchers are provided to facilitate the application and expansion of design strategies to new chemical systems. The only limit is imagination, along with some chemical, physical, and thermodynamical principles, of course.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
Owen应助<小天才>采纳,获得10
2秒前
英姑应助九思采纳,获得10
3秒前
4秒前
4秒前
4秒前
5秒前
量子星尘发布了新的文献求助10
6秒前
JamesPei应助机灵的囧采纳,获得10
7秒前
llll发布了新的文献求助10
7秒前
orixero应助xmh采纳,获得10
7秒前
wq1020发布了新的文献求助10
9秒前
10秒前
皮皮蛙完成签到,获得积分10
10秒前
情怀应助常芹采纳,获得10
11秒前
肖肖发布了新的文献求助10
11秒前
11秒前
11秒前
12秒前
缥缈问柳完成签到,获得积分10
12秒前
12秒前
明理念桃完成签到,获得积分10
13秒前
13333发布了新的文献求助10
14秒前
Ava应助不吃意面的老番茄采纳,获得10
16秒前
16秒前
zhao完成签到 ,获得积分10
18秒前
19秒前
19秒前
19秒前
xmh完成签到,获得积分10
20秒前
什么也难不倒我完成签到 ,获得积分10
20秒前
21秒前
孟一发布了新的文献求助30
21秒前
22秒前
小幻完成签到,获得积分10
22秒前
好宝宝发布了新的文献求助10
23秒前
23秒前
乐天完成签到,获得积分10
24秒前
wuniuniu发布了新的文献求助10
24秒前
Happyness应助13333采纳,获得30
25秒前
25秒前
高分求助中
A new approach to the extrapolation of accelerated life test data 1000
ACSM’s Guidelines for Exercise Testing and Prescription, 12th edition 500
‘Unruly’ Children: Historical Fieldnotes and Learning Morality in a Taiwan Village (New Departures in Anthropology) 400
Indomethacinのヒトにおける経皮吸収 400
Phylogenetic study of the order Polydesmida (Myriapoda: Diplopoda) 370
基于可调谐半导体激光吸收光谱技术泄漏气体检测系统的研究 350
Robot-supported joining of reinforcement textiles with one-sided sewing heads 320
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3988838
求助须知:如何正确求助?哪些是违规求助? 3531250
关于积分的说明 11252914
捐赠科研通 3269838
什么是DOI,文献DOI怎么找? 1804820
邀请新用户注册赠送积分活动 881943
科研通“疑难数据库(出版商)”最低求助积分说明 809028