Anti-counterfeiting tags with camouflaged QR codes on nanocavities, using polymer-dispersed-liquid-crystals

Counterfeiting poses an evergrowing challenge, driving the need for innovative and sophisticated anti-counterfeiting strategies and technologies. Many solutions focus on tags characterized by optical features that are partially or completely camouflaged to the human eye, thus discouraging scammers. In this paper, a QR code is laser printed on a thin plastic foil previously coated by a specific nanocavity consisting of a metal/insulator/metal/insulator (MIMI) multilayer. This metamaterial possesses unique features in terms of light transmission that are due to the specific design. A thin layer of polymer dispersed liquid crystals, fabricated incorporating specific nematic liquid crystals in a polymer matrix, is able to camouflage the QR code that becomes, then, readable only under specific thermal conditions. Three anti-counterfeiting tags were fabricated, each using a distinct LC with its own nematic-isotropic transition temperature. The peculiar combination of the unique optical properties of nematic liquid crystals and optical nanocavities results in the creation of a novel type of tags showing two different encoding levels. Stress tests including water immersion, bending test, and prolonged heating have been performed ensuring the long-term stability of the tags. The realized two security-level anti-counterfeiting tags are cost-effective, straightforward to manufacture and, thanks to their flexibility, can be easily integrated into packaging and products.