Customized flexible iontronic pressure sensors: Multilevel microstructures by 3D-Printing for enhanced sensitivity and broad pressure range

• An altering of the sensor’s sensitivity threshold iontronic pressure sensor is fabricated. • The sensor also possesses anti-freezing performance. • It is demonstrated a convenient, less-cost, and highly efficient method to fabricate wearable electronics. Flexible capacitive pressure sensors stand out for their energy efficiency, rapid responsiveness, and exceptional durability, with their performance hinging on the intricate design of microstructures and the strategic selection of dielectric materials. However, creating cost-effective and practical fabrication methods for these components continues to pose a significant challenge. This study unveils an innovative iontronic flexible pressure sensor that integrates an ionic layer with sophisticated multilayer microstructures, setting new benchmarks in pressure sensing technology. The sensor operates within an expansive pressure range, achieving sensitivities as high as 92.14 kPa −1 at pressures from 0 to 50 kPa, and 22.96 kPa −1 at pressures ranging from 50 to 800 kPa, demonstrating extraordinary sensitivity. It also achieves an exceptionally low detection limit of 6.67 Pa and features swift response times of 56 ms to activate and 18 ms to deactivate. Enhanced by the addition of CuSO 4 , the sensor not only withstands freezing conditions but also significantly boosts sensitivity. Moreover, this sensor is capable of detecting human joint movements and subtle pressure fluctuations under high-pressure conditions, suggesting a breakthrough in the field. This research presents a simple, reliable, and cost-efficient method for developing flexible iontronic pressure sensors, poised to revolutionize applications in wide-ranging pressures and adverse temperature environments.