材料科学
流延
氧化钇稳定氧化锆
金属陶瓷
烧结
多孔性
水溶液
固体氧化物燃料电池
立方氧化锆
复合材料
氧化物
铜
石墨
阳极
铸造
冶金
化学工程
陶瓷
物理化学
化学
工程类
电极
作者
Diana-María Amaya-Dueñas,Daniel Estrada,Dachamir Hotza,João Batista Rodrigues Neto,Jairo Arturo Escobar
标识
DOI:10.1016/j.jeurceramsoc.2017.05.002
摘要
Porous copper/yttria-stabilized zirconia (Cu/YSZ) thin tapes were produced to be used as anodes in intermediate temperature solid oxide fuel cells (IT-SOFC). The use of copper in these cermets promises a better chemical resistance and a lower operating temperature for SOFC. Graphite and cassava starch were used as pore forming agents, which led to porosity values between 30 and 40%. Tapes were obtained by aqueous tape casting with controlled thickness (300–2000 μm). Before casting, CuO/YSZ aqueous suspensions were formulated based on rheological characterization. Sintering was carried out at 1150 °C during 1 h. Cu/YSZ tapes were obtained after redox reaction, performed at 400, 600 and 800 °C.
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