催化作用
煅烧
铜
无机化学
化学
X射线光电子能谱
化学吸附
热脱附光谱法
选择性
解吸
程序升温还原
吸附
核化学
化学工程
物理化学
有机化学
工程类
作者
Tao Ding,Hua Tian,Jichang Liu,Wenyuan Wu,Jin‐Tao Yu
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2016-04-01
卷期号:37 (4): 484-493
被引量:20
标识
DOI:10.1016/s1872-2067(15)61053-1
摘要
Cu/SiO2 catalysts prepared by the ammonia evaporation method were applied to hydrogenation of diethyl malonate to 1,3-propanediol. The calcination temperature played an important role in the structural evolution and catalytic performance of the Cu/SiO2 catalysts, which were systematically characterized by N2 adsorption-desorption, inductively coupled plasma-atomic emission spectroscopy, N2O chemisorption, X-ray diffraction, Fourier transform infrared spectroscopy, H2 temperature-programmed reduction, transmission electron microscopy, and X-ray photoelectron spectroscopy. When the Cu/SiO2 catalyst was calcined at 723 K, 90.7% conversion of diethyl malonate and 32.3% selectivity of 1,3-propanediol were achieved. Compared with Cu/SiO2 catalysts calcined at other temperatures, the enhanced catalytic performance of the Cu/SiO2 catalyst calcined at 723 K can be attributed to better dispersion of copper species, larger cupreous surface area and greater amount of copper phyllosilicate, which results in a higher ratio of Cu+/Cu0. The synergetic effect of Cu0 and Cu+ is suggested to be responsible for the optimum activity.
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