Thermoelectric Power of Silver Telluride Thin Films and its Thermal Conductivity Applications

碲化铋 塞贝克系数 热电效应 薄膜 纳米线 热电材料 材料科学 单斜晶系 扫描电子显微镜 热导率 分析化学(期刊) 光电子学 化学 纳米技术 结晶学 晶体结构 复合材料 物理 色谱法 热力学
作者
M. Prem Nawaz,M. Palanivelu,M. Karunanithy,A. Afroos Banu,A. Ayeshamariam,K. Kaviyarasu
出处
期刊:Asian Journal of Chemistry [ASIAN PUBLICATION CORPORATION]
卷期号:33 (11): 2615-2620
标识
DOI:10.14233/ajchem.2021.23380
摘要

The hydrothermal technique was used to create straight single crystal silver telluride nanowires with a diameter of around 200 nm and a length of up to micrometers of decades. There has been no template or surfactant used in the process. As-synthesized products are high purity and well-crystallized, confirmed by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectrum, transmission electron microscopy (TEM), and a high-resolution SAED pattern. Differential scanning calorimetry was used to observe the reversible structural phase shift from the low-temperature monoclinic structure to the high-temperature face-centered cubic structure. Furthermore, the dramatic drop in electrical current in a single nanowire at the phase transition temperature is revealed, paving the way for future research into the manufacturing of one-dimensional nanoscale devices. Silver telluride (Ag2Te) has large thermoelectric coefficients and it was tested by using resistor graph and calculated the values of it, thermal conductivity and Seebeck coefficient were discussed with respect to the temperature of thin films. Semiconductors were superior thermoelectric material due to higher ratio of electrical and thermal conductivities. Therefore, the AgTe thin films deposited on indium tin oxide (ITO) substrates were employed, thermoelectric power and thermal conductivity measurements, respectively.

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