荧光
检出限
焦磷酸盐
化学
半胱胺
选择性
量子点
猝灭(荧光)
线性范围
水溶液
光化学
分析化学(期刊)
色谱法
材料科学
纳米技术
生物化学
物理化学
物理
催化作用
酶
量子力学
作者
Tuanjai Noipa,Kessarin Ngamdee,Thawatchai Tuntulani,Wittaya Ngeontae
标识
DOI:10.1016/j.saa.2013.08.067
摘要
A new sensitive and selective fluorescence sensor for the detection of pyrophosphate (PPi) in aqueous media based on the Fe3+ decorated cysteamine CdS QDs ([Cys-CdS QDs]–Fe3+) was proposed. The presence of PPi can induce the fluorescence quenching of [Cys-CdS QDs]–Fe3+ due to the high formation constants between the phosphate group and Fe3+. Because the complex between Fe3+ and PPi acts as an efficient quencher, the concentration of PPi can be evaluated by tracking the degree of fluorescence quenching. The fabricated sensor was optimized to obtain the best sensor selectivity and sensitivity. Under optimal conditions, a linear relationship between the fluorescence response and the concentration of PPi was established in the range of 0.5–10 μM. The limits of detection and quantitation for PPi were found to be 0.11 and 2.78 μM, respectively. Furthermore, the proposed sensor exhibited high selectivity toward PPi relative to other common anions. The proposed sensor was successfully applied to the detection of PPi in urine samples with satisfactory results.
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