Hybridization of Palladium Nanoparticles with Aromatic‐Rich SU‐101 Metal‐Organic Framework for Effective Transfer Hydrogenation

Abstract Metal‐organic frameworks (MOFs) are crystalline porous materials with designable pores. In this study, we loaded Pd nanoparticles onto π‐electron rich pores of ellagic acid based SU‐101 MOF (Bi 2 O(H 2 O) 2 (C 14 H 2 O 8 ) ⋅ nH 2 O) in order to surround Pd active sites with π‐electron rich environment. The material has been explored for the transformation of 4‐Nitro phenol (4‐NP) to 4‐Amino phenol (4‐AP) using ammonia borane (AB). AB acted as efficient transfer hydrogenation agent compared to NaBH 4 because of its ability to transfer hydrogens at milder conditions. AB is safer and easy to handle compared to molecular hydrogen or NaBH 4 . The Pd NPs are loaded on to SU‐101 using two methodologies. One by supporting preformed Pd NPs onto MOF surface (Pd‐WCGA/SU‐101) and the other by wet impregnation method (Pd/SU‐101). The later method yields a material with strong interaction between Pd and SU‐101. The Pd/SU‐101 exhibited superior activity for 4‐NP reduction (turn over frequency=2421 h −1 ) using AB due to an enrichment of 4‐NP around Pd active sites by π‐electron rich pore environment.