Polypyrrole supported Pd/Fe bimetallic nanoparticles with enhanced catalytic activity for simultaneous removal of 4-chlorophenol and Cr(VI)

Nanoscale zerovalent iron (nZVI) represents a promising reduction technology for water remediation, but its broad application is largely hampered by the tendency of nZVI to aggregate and the low electron transferability due to the interfacial charge resistance. Herein, by combining the advantages of polypyrrole (PPY) and nZVI, we prepared a composite material (i.e., PPY supported palladium‑iron bimetallic nanoparticles (Pd/Fe@PPY)) and applied it for the simultaneous removal of 4-chlorophenol (4-CP) and Cr(VI). Our results showed that this material had superior catalytic performances with a complete removal of 4-CP (50 mg·L-1) and Cr(VI) (10 mg·L-1) within 60 and 1 min, respectively. As opposed to the bare Pd/Fe nanoparticles, the reactivity of Pd/Fe@PPY with 4-CP was significantly enhanced by nearly 8 times. The enhanced catalytic activity of Pd/Fe@PPY was attributed to the distinctive properties of PPY as i) a good support that resulted in the formation of Pd/Fe nanoparticles with high dispersibility; ii) an adsorbent that increased the accessibility of 4-CP and Cr(VI) with electrons or active species (e.g., H*) on the particles surface; iii) an electron transfer carrier that facilitated the reactivity of Pd/Fe@PPY with contaminants by reducing the interfacial charge resistance. Moreover, by conducting cyclic voltammetry and quenching investigations, we showed that two mechanisms (i.e., direct and H*-mediated indirect electron transfer) were involved in the reductive dehalogenation of 4-CP, while catalytic hydrodechlorination played a dominant role. This work offers an alternative material for the efficient removal of 4-CP and Cr(VI) and provides better understanding of the relationship between structure and catalytic activity of nZVI.