催化作用
微型多孔材料
分子
化学
沸石
烯烃
溶剂
结晶学
组态熵
物理化学
立体化学
化学工程
化学物理
热力学
有机化学
物理
工程类
作者
Daniel T. Bregante,Matthew Chan,Jun Zhi Tan,E. Zeynep Ayla,Christopher P. Nicholas,Diwakar Shukla,David W. Flaherty
标识
DOI:10.26434/chemrxiv.13288805
摘要
Solvent structures that surround active sites reorganize during catalysis and influence the stability of surface intermediates. Within the pores of a zeolite, H<sub>2</sub>O molecules form hydrogen-bonded structures that differ significantly from bulk H<sub>2</sub>O. Spectroscopic measurements and molecular dynamics simulations show that H<sub>2</sub>O molecules form bulk-like three-dimensional structures within 1.3 nm cages, while H<sub>2</sub>O molecules coalesce into oligomeric one-dimensional chains distributed throughout zeolite frameworks when the pore diameter is smaller than 0.65 nm. The differences between the motifs of these solvent structures provide opportunities to manipulate enthalpy-entropy compensation relationships and significantly increase rates of catalytic turnover events. Here, we explain how the reorganization of these pore size-dependent H<sub>2</sub>O structures during alkene epoxidation catalysis gives rise to entropy gains that increase turnover rates by up to 400-fold. Collectively, this work shows how solvent molecules form discrete structures with highly correlated motion within microporous environments, and that the reorganization of these structures may be controlled to confer stability to reactive intermediates.
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