Contact‐electro‐catalysis for Direct Synthesis of H2O2 under Ambient Conditions

Hydrogen peroxide (H2 O2 ) is an indispensable basic reagent in various industries, such as textile bleach, chemical synthesis, and environmental protection. However, it is challenging to prepare H2 O2 in a green, safe, simple and efficient way under ambient conditions. Here, we found that H2 O2 could be synthesized using a catalytic pathway only by contact charging a two-phase interface at room temperature and normal pressure. Particularly, under the action of mechanical force, electron transfer occurs during physical contact between polytetrafluoroethylene particles and deionized water/O2 interfaces, inducing the generation of reactive free radicals (⋅OH and ⋅O2- ), and the free radicals could react to form H2 O2 , yielding as high as 313 μmol L-1 h-1 . In addition, the new reaction device could show long-term stable H2 O2 production. This work provides a novel method for the efficient preparation of H2 O2 , which may also stimulate further explorations on contact-electrification-induced chemistry process.