材料科学
线性低密度聚乙烯
复合材料
聚烯烃
低密度聚乙烯
高密度聚乙烯
聚乙烯
电介质
光电子学
图层(电子)
作者
Jingguo Qu,Shihang Wang,Liuqing Yang,Huanfeng Jiang,Yifan Wu,Luwei Du,Zejia Wang,Lingqi Guo
标识
DOI:10.1016/j.polymdegradstab.2023.110573
摘要
Exploring methods of improving the performance of high-voltage cable XLPE insulation is a hot issue in high-voltage and insulation technology. This paper presented a new method to improve the physical properties of XLPE by doping low-content polyolefin materials, such as LLDPE or HDPE. The new XLPE insulation has significantly improved high-temperature mechanical properties and slightly improved room-temperature mechanical properties. The optimal thermal elongation properties were achieved with a 1 phr content of HDPE and LLDPE, while DC conductivity, DC breakdown strength, and dielectric properties were stable or slightly improved. The properties mentioned above showed a decreasing trend at higher content. This study demonstrated that adding HDPE or LLDPE to LDPE increases the physical entanglement of XLPE molecular chains, which has a similar effect to crosslinks formed by chemical crosslinking in enhancing the mechanical properties of XLPE insulation. This suggests that there is a potential to reduce the concentration of crosslinking agents during XLPE cable manufacturing while maintaining electrical properties and improving mechanical properties at elevated temperatures. It provides a new idea for improving the properties of XLPE insulation for high-voltage DC cables.
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