The enhanced physical properties of XLPE insulation for high voltage cable based on LDPE/LLDPE or LDPE/HDPE blends

材料科学 线性低密度聚乙烯 复合材料 聚烯烃 低密度聚乙烯 高密度聚乙烯 聚乙烯 电介质 光电子学 图层(电子)
作者
Jinfei Qu,Shihang Wang,Shengtao Li,Hongjian Liu,Yifan Wu,Luwei Du,Zejia Wang,Lingqi Guo
出处
期刊:Polymer Degradation and Stability [Elsevier BV]
卷期号:218: 110573-110573 被引量:15
标识
DOI:10.1016/j.polymdegradstab.2023.110573
摘要

Exploring methods of improving the performance of high-voltage cable XLPE insulation is a hot issue in high-voltage and insulation technology. This paper presented a new method to improve the physical properties of XLPE by doping low-content polyolefin materials, such as LLDPE or HDPE. The new XLPE insulation has significantly improved high-temperature mechanical properties and slightly improved room-temperature mechanical properties. The optimal thermal elongation properties were achieved with a 1 phr content of HDPE and LLDPE, while DC conductivity, DC breakdown strength, and dielectric properties were stable or slightly improved. The properties mentioned above showed a decreasing trend at higher content. This study demonstrated that adding HDPE or LLDPE to LDPE increases the physical entanglement of XLPE molecular chains, which has a similar effect to crosslinks formed by chemical crosslinking in enhancing the mechanical properties of XLPE insulation. This suggests that there is a potential to reduce the concentration of crosslinking agents during XLPE cable manufacturing while maintaining electrical properties and improving mechanical properties at elevated temperatures. It provides a new idea for improving the properties of XLPE insulation for high-voltage DC cables.
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