Pressure-induced Emission in 0D Metal Halide (EATMP)SbBr5 by Regulating Exciton–Phonon Coupling

卤化物 激子 联轴节(管道) 声子 金属 材料科学 凝聚态物理 物理 化学 无机化学 冶金
作者
Jiayuan Liang,Xin Mi,Songhao Guo,Hui Luo,Kejun Bu,Tonghuan Fu,menglin duan,Yang Wang,Qingyang Hu,Ren‐Gen Xiong,Peng Qin,Fuqiang Huang,Xujie Lü
出处
期刊:Chinese Journal of Structural Chemistry 卷期号:43 (7): 100333-100333 被引量:1
标识
DOI:10.1016/j.cjsc.2024.100333
摘要

Zero-dimensional (0D) hybrid metal halides are considered as promising light-emitting materials due to their unique broadband emission from self-trapped excitons (STEs). Despite substantial progress in the development of these materials, the photoluminescence quantum yields (PLQY) of hybrid Sb-Br analogs have not fully realized the capabilities of these materials, necessitating a better fundamental understanding of the structure–property relationship. Here, we have achieved a pressure-induced emission in 0D (EATMP)SbBr5 (EATMP = (2-aminoethyl)trimethylphosphanium) and the underlying mechanisms are investigated using in situ experimental characterization and first-principles calculations. The pressure-induced reduction in the overlap between STE states and the ground state results in the suppression of phonon-assisted non-radiative decay. The PL evolution is systematically demonstrated to be controlled by the pressure-regulated exciton–phonon coupling, which can be quantified using Huang–Rhys factor S. Through detailed studies of the S-PLQY relation in a series of 0D hybrid antimony halides, we establish a quantitative structure–property relationship that regulating S value toward 21 leads to the optimized emission. This work not only sheds light on pressure-induced emission in 0D hybrid metal halides but also provides valuable insights into the design principles for enhancing the PLQY in this class of materials.
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