化学
生物医学中的光声成像
光纤
微量气体
跟踪(心理语言学)
气体分析
分析化学(期刊)
光学
环境化学
语言学
物理
哲学
有机化学
作者
Xinyu Zhao,Yajie Zhang,Xiao Han,Hongchao Qi,Fengxiang Ma,Ke Chen
出处
期刊:Analytical Chemistry
[American Chemical Society]
日期:2024-06-26
卷期号:96 (27): 10995-11001
被引量:25
标识
DOI:10.1021/acs.analchem.4c01480
摘要
A high-sensitivity fiber-optic photoacoustic sensor with pressure compensation is proposed to analyze the decomposition component SO2 in high-pressure gas insulation equipment. The multiple influence mechanism of pressure on photoacoustic excitation and cantilever detection has been theoretically analyzed and verified. In the high-pressure environment, the excited photoacoustic signal is enhanced, which compensates for the loss of sensitivity of the cantilever. A fiber-optic F-P cantilever is utilized to simultaneously measure static pressure and dynamic photoacoustic wave, and a spectral demodulation method based on white light interference is applied to calculate the optical path difference of the F-P interferometer (FPI). The real-time pressure is judged through the linear relationship between the average optical path difference of FPI and the pressure, which gives the proposed fiber-optic photoacoustic sensor the inherent advantages of being uncharged and resistant to electromagnetic interference. The average optical path difference of FPI is positively related to pressure, with a responsivity of 0.6 μm/atm, which is based on changes in the refractive index of gas. In the range of 1-4 atm, the SO2 sensor has a higher detection sensitivity at high-pressure, which benefits from the pressure compensation effect. With the pressure environment of gas insulation equipment at 4 atm as the application background, the SO2 gas is tested. The detection limit is 20 ppb with an averaging time of 400 s.
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