Pillared-MOF@NiV-LDH Composite as a Remarkable Electrocatalyst for Water Oxidation

Oxygen evolution reaction (OER) represents a highly important electrochemical transformation in energy storage and conversion technologies. Considering the low rate of this four-electron half-reaction, there is a demand for efficient, stable, and noble-metal-free electrocatalysts to improve the kinetic and economical parameters. In this work, a new pillared-MOF@NiV-LDH nanocomposite based on a CoII metal-organic framework (pillared-MOF) and heterometallic Ni/V-layered double hydroxide (NiV-LDH) was assembled via a simple protocol, characterized, and explored as an electrocatalyst in OER. A remarkable electrocatalytic efficiency of pillared-MOF@NiV-LDH in 1 M KOH is evidenced by a low overpotential (238 mV at 10 mA cm-2 current density) and a small value of the Tafel slope (62 mV dec-1). These parameters are very close to those of the reference IrO2 electrocatalyst and are superior to the majority of the LDH- and MOF-based systems previously applied for OER. Excellent stability of pillared-MOF@NiV-LDH was confirmed by the chronopotentiometry tests for 70 h and linear-sweep voltammetry after 7000 cycles. Features such as rich electroactive sites, porous structure, high surface area, and synergic effect between pillared-MOF and NiV-LDH are likely responsible for the remarkable electrocatalytic efficiency of this electrocatalyst in OER. Despite prior reports on the application of NiV-LDH in OER, the present study describes the first example where this type of LDH is blended with MOF to generate a nanocomposite material. The interface between the two components of the composite can improve the electronic structure and, in turn, the electrocatalytic behavior. The introduction of this composite paves the way toward the synthesis of other multicomponent materials with potential applications in different energy fields.