相界
四方晶系
极化
相图
材料科学
正交晶系
凝聚态物理
铁电性
单晶
相(物质)
单一领域
结晶学
电介质
磁畴
化学
晶体结构
物理
磁化
磁场
光电子学
有机化学
量子力学
作者
Yaming Zhou,Qiang Liu,Chao Xu,Fangping Zhuo,Donglin Liu,Qingfeng Yan,Shujun Zhang,Xiangcheng Chu
摘要
Based on the domain configuration analysis, we demonstrate that orthorhombic (O) phase is a structural bridge between the rhombohedral (R) and tetragonal (T) phase in Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT) crystals near the morphotropic phase boundary (MPB), as illustrated in the composition-temperature phase diagram. After poling along the polar direction, domain patterns in PMN-0.30PT, PMN-0.33PT, and PMN-0.37PT single crystals are found to accord with quasisingle-domain configurations (1R*, 1O*, and 1T*) after removal of the electric field. Furthermore, by the thermodynamic theory analysis, the quasisingle-domain states present one dominant domain and other adjacent domains owing to partial depolarization. Our results provide a reliable and nondestructive method to identify the phase structures near the MPB region in the PMN-xPT and other similar relaxor-ferroelectric single crystals.
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