One-Pot Preparation of Carboxylated Cellulose Nanocrystals and Their Liquid Crystalline Behaviors

氧化剂 高锰酸钾 草酸 结晶度 硫酸 化学工程 纤维素 产量(工程) 水解 材料科学 抗坏血酸 纳米晶 晶体结构 化学 无机化学 有机化学 纳米技术 复合材料 工程类 食品科学
作者
Lijuan Zhou,Na Li,Jie Shu,Yunxiao Liu,Kuntao Wang,Xiang Cui,Yuan Yuan,Beibei Ding,Yong Geng,Zhaolu Wang,Yongxin Duan,Jianming Zhang
出处
期刊:ACS Sustainable Chemistry & Engineering [American Chemical Society]
卷期号:6 (9): 12403-12410 被引量:84
标识
DOI:10.1021/acssuschemeng.8b02926
摘要

Carboxylated cellulose nanocrystals (CNCs-COOH) have attracted great attention for their potential applications in reinforcing polymer materials and surface modification. Herein, we developed a low-cost approach to prepare CNCs-COOH from pulp with high yield at mild reaction conditions (50 °C, 1 wt % sulfuric acid medium) using potassium permanganate (KMnO4) and oxalic acid (OA, H2C2O4) as the oxidizing and reducing agents, respectively. The oxidant dosage in this strategy is much lower than that in a conventional TEMPO method, and the yield of CNCs-COOH can reach as high as 68.0%, with a carboxylate content of 1.58 mmol/g. In this reaction system, the presence of the OA can complex with Mn3+ to form [Mn(C2O42–)]+ and prevent the Mn3+ from being reduced to Mn2+, leading to the strong oxidizing capacity of the reaction system maintained for a longer time. Atomic force microscopy analysis showed that rod-like CNCs were obtained with an average size of 10–22 nm in diameter and 150–300 nm in length. The crystal structure of as-prepared CNCs-COOH was nearly unchanged, and the crystallinity was 89.2% based on WAXD analysis. Of particular interest, CNCs-COOH suspension with high concentration (>6 wt %) also exhibited the same intriguing chiral nematic liquid crystalline self-assembly behaviors as sulfate CNCs prepared by traditional H2SO4 hydrolysis method. This study provides an efficient and cost-effective way to fabricate CNCs-COOH, leading to great potential applications in constructing advanced functional material.
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