化学
分子内力
分子间力
芳基
呋喃
醌
立体化学
组合化学
分子
有机化学
烷基
作者
Paolo Lupattelli,Teresa Laurita,Rosarita D’Orsi,Lucia Chiummiento,Maria Funicello
出处
期刊:Synthesis
[Georg Thieme Verlag KG]
日期:2020-03-16
卷期号:52 (10): 1451-1477
被引量:31
标识
DOI:10.1055/s-0039-1690820
摘要
This review gives an overview on recent developments in methods for the construction of compounds with the 2,3-dihydrobenzofuran core in the period 2012 to 2019. Interest in 2,3-dihydrobenzofurans is constantly increasing. The methods are divided into intermolecular and intramolecular approaches. Intermolecular approaches are subdivided according to the parent intermediate for the key reaction, while intermolecular approaches are subdivided according by which bond is formed in the key reaction. The transformation of benzofurans to dihydrobenzofurans and other miscellaneous methods are also discussed. Approaches useful for the synthesis of natural products are emphasized. 1 Introduction 2 Intermolecular Approaches 2.1 o-Quinone Methides and o-Quinones 2.2 p-Quinone Methides and p-Quinones 2.3 Nitrogen-Containing Phenols and Quinones 2.4 o-Hydroxyphenylcarbonyl Derivatives and Phenols 2.5 Miscellaneous 3 Intramolecular Approaches 3.1 O–C2 Bond Forming 3.2 C2–C3 Bond Forming 3.3 C3–Aryl Bond Forming 3.4 O–Aryl Bond Forming 4 From BF to DHB 5 Rearrangements and Aromatizations
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