Direct versus acetalization routes in the reaction network of catalytic HMF etherification

The etherification of HMF (5-hydroxymethylfurfural) to EMF (5-(ethoxymethyl)furan-2-carbaldehyde) is studied over a series of MFI-type zeolite catalysts containing different heteroatoms (B, Fe, Al), aiming to understand the effect of different isomorph substitutions in the MFI framework on the reaction pathways of HMF conversion.