Zinc and nitrogen ornamented bluish white luminescent carbon dots for engrossing bacteriostatic activity and Fenton based bio-sensor

发光 碳纤维 量子点 材料科学 荧光 检出限 杂原子 生物分子 生物传感器 过氧化氢 光化学 纳米技术 化学 有机化学 光电子学 戒指(化学) 冶金 复合材料 物理 复合数 量子力学 色谱法
作者
Poushali Das,Sayan Ganguly,Madhuparna Bose,Subhadip Mondal,Sumita Choudhary,S. Gangopadhyay,Amit Kumar Das,Susanta Banerjee,Narayan Chandra Das
出处
期刊:Materials Science and Engineering: C [Elsevier]
卷期号:88: 115-129 被引量:98
标识
DOI:10.1016/j.msec.2018.03.010
摘要

Carbon dots with heteroatom co-doping associated with consummate luminescence features are of acute interest in diverse applications such as biomolecule markers, chemical sensing, photovoltaic, and trace element detection. Herein, we demonstrate a straightforward, highly efficient hydrothermal dehydration technique to synthesize zinc and nitrogen co-doped multifunctional carbon dots (N, Zn-CDs) with superior quantum yield (50.8%). The luminescence property of the carbon dots can be tuned by regulating precursor ratio and surface oxidation states in the carbon dots. A unique attribution of the as-prepared carbon dots is the high monodispersity and robust excitation-independent emission behavior that is stable in enormously reactive environment and over a wide range of pH. These N, Zn-CDs unveils captivating bacteriostatic activity against gram-negative bacteria Escherichia coli. Furthermore, the excellent luminescence properties of these carbon dots were applied as a platform of sensitive biosensor for the detection of hydrogen peroxide. Under optimized conditions, these N, Zn-CDs reveals high sensitivity over a broad range of concentrations with an ultra-low limit of detection (LOD) indicating their pronounced prospective as a fluorescent probe for chemical sensing. Overall, the experimental outcomes propose that these zero-dimensional nano-dots could be developed as bacteriostatic agents to control and prevent the persistence and spreading of bacterial infections and as a fluorescent probe for hydrogen peroxide detection.
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