材料科学
曲率
弯曲
电导率
Crystal(编程语言)
变形(气象学)
结晶
光电子学
单晶
光电效应
纳米技术
复合材料
结晶学
计算机科学
化学工程
几何学
化学
数学
物理化学
工程类
程序设计语言
作者
Yifu Chen,Zewei Chang,Jiaxing Zhang,Junbo Gong
标识
DOI:10.1002/anie.202108441
摘要
Abstract Electronic microdevices of self‐bending coronene crystals are developed to reveal an unexplored link between mechanical deformation and crystal function. First, a facile approach towards length/width/curvature‐controllable micro‐crystals through bottom‐up solution crystallization was proposed for high processability and stability. The bending crystal devices show a significant increase beyond seven orders of magnitude in conductivity than the straight ones, providing the first example of deformation‐induced function enhancement in crystal materials. Besides, double effects caused by bending, including the change of π electron level as well as the enhancement of carrier mobility, were determined, respectively by the X‐ray photoelectric spectroscopy and X‐ray crystallography to coexist, contributing to the conductivity improvement. Our findings will promote future creation of flexible organic crystal systems with deformation‐enhanced functional features towards customized smart devices.
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