电致发光
圆极化
分子
光致发光
材料科学
白光
对映体
化学
光电子学
光学
物理
立体化学
纳米技术
图层(电子)
量子力学
微带线
作者
Pei Zhao,Wei‐Chen Guo,Meng Li,Haiyan Lu,Chuan‐Feng Chen
标识
DOI:10.1002/anie.202409020
摘要
The strategy of integrating conformational isomerization donors and chiral acceptors in a single molecule was proposed to construct white circularly polarized luminescence (WCPL) materials in this work. Consequently, a pair of dual-emission enantiomers, namely (R/S)-DO-PTZ, were designed and synthesized, which displayed white emission with blue and yellow dual-emission bands in solution and solid films with Commission Internationale de l'Eclairage (CIE) coordinates of (0.30, 0.33) and (0.33, 0.35), respectively. Meanwhile, (R/S)-DO-PTZ exhibited a high PLQY of up to 67 % in doped films and clear mirror-image WCPL signals with a |g
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