超分子化学
聚合
聚合物
单体
不对称
超分子聚合物
材料科学
高分子化学
化学
结晶学
有机化学
晶体结构
量子力学
物理
作者
Angshuman Das,Saikat Ghosh,Subi J. George
标识
DOI:10.1002/anie.202413747
摘要
The amplification of asymmetry in supramolecular polymers has recently garnered significant attention. While asymmetry amplification has predominantly been explored under thermodynamic conditions, the kinetic aspect of this process unveils intriguing observations, yet is scarcely reported in the literature. Herein, drawing inspiration from macromolecular systems, we propose a novel strategy for enhancing asymmetry in supramolecular polymers through a seed-induced supramolecular polymerization approach under kinetic conditions, employing a naphthalene diimide-derived monomer (ANSG) for template-induced supramolecular polymerization, utilizing adenosine triphosphate (ATP) and pyrophosphate (PPi) as templates. A chiral seed comprising [ANSG-ATP]
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