超分子化学
聚合
聚合物
单体
不对称
发光
超分子聚合物
材料科学
模板
化学
光化学
纳米技术
结晶学
晶体结构
光电子学
物理
量子力学
复合材料
作者
Angshuman Das,Saikat Ghosh,Subi J. George
标识
DOI:10.1002/anie.202413747
摘要
The amplification of asymmetry in supramolecular polymers has recently garnered significant attention. While asymmetry amplification has predominantly been explored under thermodynamic conditions, the kinetic aspect of this process unveils intriguing observations, yet is scarcely reported in the literature. Herein, drawing inspiration from macromolecular systems, we propose a novel strategy for enhancing asymmetry in supramolecular polymers through a seed‐induced supramolecular polymerization approach under kinetic conditions, employing a naphthalene diimide‐derived monomer (ANSG) for template‐induced supramolecular polymerization, utilizing adenosine triphosphate (ATP) and pyrophosphate (PPi) as templates. A chiral seed comprising [ANSG‐ATP]S effectively amplifies the overall supramolecular asymmetry when exposed to a mixture of achiral templates (PPi) and monomers (ANSG), owing to its efficient seeding characteristics under kinetic conditions. As a result of efficient co‐operativity, conversely, employing an achiral seed [ANSG‐PPi]S in a mixture of chiral templates (ATP) and monomers (ANSG) results in the attenuation of asymmetry, highlighting the effective modulation achievable through the seeding approach, ‐an unprecedented observation in the field. Exploiting the efficient aggregation‐induced emission enhancement (AIEE) of the resultant supramolecular polymers further extends the amplification and attenuation of circularly polarized luminescence (CPL) as a potential function.
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