硫系化合物
材料科学
钙钛矿(结构)
光电子学
发光二极管
发光
兴奋剂
卤化物
吸收(声学)
紫外线
无机化学
结晶学
化学
复合材料
作者
Yurun Liang,Jiang Li,Zhipeng Chen,Gaoqiang Li,Mengyao Li,Mochen Jia,Xu Chen,Xinjian Li,Yanbing Han,Zhifeng Shi
标识
DOI:10.1002/adom.202301977
摘要
Abstract Chalcogenide perovskites are an emerging family of perovskite materials, which possess excellent optoelectronic properties comparable with halide perovskites, avoiding the drawbacks of toxicity and poor stability. Due to the superiorities of strong light absorption, direct bandgaps, excellent carrier transport abilities, high defect tolerance, robust stability, and non‐toxicity, chalcogenide perovskites have been extensively studied as photovoltaic materials. However, the light emitting potential of chalcogenide perovskites is ignored or less explored. In this work, an Eu 2+ doping strategy is proposed to activate the light emitting abilities of chalcogenide perovskite. The synthesized SrHfS 3 :Eu 2+ powder exhibits intense red emission of Eu 2+ through the relaxation of 4f 6 5d 1 to 4f 7 5d 0 . The strong interband absorption of SrHfS 3 , as a distinct character of chalcogenide perovskite, harvests the optical energy and funnels it to the luminescent center Eu 2+ . Besides, SrHfS 3 :Eu 2+ is characterized by superior semiconducting properties, suggesting its strong potential as suitable emitters in light‐emitting diodes. Moreover, the obtained SrHfS 3 :Eu 2+ powder and its luminescence properties remain stable under ultraviolet irradiation, water, and high temperature testing. The above observations open a new frontier for exploring luminescent chalcogenide perovskites, highlighting their great potential in lighting and displays, rather than being limited to photovoltaic devices.
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