材料科学
复合材料
阻燃剂
聚苯胺
聚脲
电磁屏蔽
原位聚合
复合数
聚合
聚氨酯
聚合物
作者
Xue Bi,Kunpeng Song,Ye‐Tang Pan,Camila Barreneche,Henri Vahabi,Jiyu He,Rong Jie Yang
出处
期刊:Small
[Wiley]
日期:2023-11-09
卷期号:20 (12)
被引量:12
标识
DOI:10.1002/smll.202307492
摘要
Abstract A dodecahedral superstructure consisting of a single layer of Janus spheres containing ZIF‐67 nanodots is prepared by in situ polymerization, with ZIF‐67 and bio‐based phytic acid (PA) as templates and dopants. It is used to improve the flame retardant, electromagnetic (EMI) shielding, and thermal conductivity properties of polyurea (PUA). By adding 5 wt% polyaniline@cobalt phytate‐2.0 (PANI@Co‐PA‐2.0), the peak of heat release rate and the peak of smoke production rate are reduced by 54.9 and 59.9%, respectively. The peak of CO and CO 2 production also decreased by 46.2 and 53.1%, respectively. A decrease in the absorption intensity of aliphatic and aromatic volatiles is also observed. The fire safety of PUA is greatly improved. In addition, PUA/PANI@Co‐PA‐2.0 exhibits an EMI shielding capability of 22.4 dB with the help of reduced graphene oxide, which confirms the possibility of PUA material application in the field of electromagnetic shielding. The 5 wt% filler increases the tensile strength of the PUA matrix to 6.3 MPa, and the composite material obtains good thermal conductivity. This work provides a viable method for the preparation of a flame‐retardant, conductive, and electromagnetic refractory PUA substrate.
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